The penetration depth of charged-particles is limited to typically lessthan 100 below the surface of a material.While the number of emitted charged-particles relates to the concentrationof the affected material in the object, the energy distribution ofemitted particles is indicative of the depth of emission. Owing to theshort range of charged-particles, this depth profiling technique is limitedto subsurface or thin-layer analysis. Moreover, since the range ofa charge-particle is material dependent, the technique is used to determinethe amount of impurity in an otherwise uniform material, so thata constant value of the range is maintained. To detect charged-particles,it is necessary to position the inspected object in a vacuum chamber, toavoid energy losses in air.Charged-Particle Emission by PhotonActivationHigh-energy photons, as discussed in section 8.3, can penetrate a nucleusand release some of its protons. Some of the possible reactions are:the reaction, as in those listed in Table 8.9, the reaction, asin and the reaction, as in Theemitted protons can in principle be used for depth profiling, employingthe principle exemplified by Eq. (8.8). The emitted protons can exit asample for subsequent detection, but only if the sample is quite thin.For such a thin sample, the incident high-energy photons will hardlysuffer any interactions, for the activation to take place. Nevertheless,photonuclear activation can produce reaction products that decay byemitting high-energy beta-particles, either in the form of electrons orpositrons. For example, produces which decays by emittingbeta-particles with a maximum energy of 3.51 MeV and 0.81 s half-life.Similarly, the reaction produces a beta-emitter that decayswith half lives of 0.84 s with maximum beta-particle energy of 13 MeV,while the reaction gives rise to a positron emitter that decayswith a 2.56 s half-life and a maxim positron energy of 4.39 MeV [13].These reactions have threshold-energies of 12 MeV for 19 MeV forand 15.24 MeV for The high-energy of emitted betaparticlesand their low mass give them higher penetrability than heaviercharged-particles, thus can be used for the analysis of lithium, berylliumand sulfur [259]. The short-half life of the reaction products either enableson-line (immediate) detection, or requires a rapid transfer systemfor delayed analysis away from the photon source.Electrons can also be emitted from the atom by Compton scatteringand the photoelectric effect. Therefore, electrons emitted by a materialexposed to x-rays can be used to radiograph its surface. Most of the
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