SAFETY DATA SHEETEthephon 85% TCSec

SAFETY DATA SHEET
Ethephon 85% TC
Section 1. Product and Company Identification
Product Name: Ethephon 85% TC
Molecular Formula: C2H6ClO3P
Molecular Weight: 144.5
Chemical Name: 2­chloroethylphosphonic acid
CAS No.: 16672­87­0
Supplier: SINO OCEAN ENTERPRISES LIMITED. Address: RM D , 12/F ., SAI WAN HO BLDG ., 45­56 SAI WAN HO STREET , HONG KONG
Section 2. Composition/Information on Ingredients
Composition CAS No. Content (%)
Ethephon 16672­87­0 85.0
Other ingredients 15.0
Section 3. Hazards Identification
Eye:Causes eye irritation. Skin: Causes skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause cardiac
disturbances. May cause central nervous system depression. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. May cause cardiac abnormalities. Chronic: Effects may be delayed. Section 4. First Aid Measures
Ingestion: If swallowed, wash out mouth with water provided person is conscious. Call a physician. Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. Skin: In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove
contaminated clothing and shoes. Call a physician. Eyes: In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure
adequate flushing by separating the eyelids with fingers. Call a physician. Section 5. Fire Fighting Measures
General Information: As in any fire, wear a self­contained breathing apparatus in pressure­demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic
gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas. Contact with metals may evolve flammable
hydrogen gas. Containers may explode when heated. Non­combustible, substance itself does not burn but
may decompose upon heating to produce irritating, corrosive and/or toxic fumes. Runoff from fire control or
dilution water may cause pollution. Extinguishing Media: Do NOT get water inside containers. For small fires, use dry chemical, carbon
dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol­resistant foam, or water
spray. Cool containers with flooding quantities of water until well after fire is out. Suitable extinguishing media: Dry inert chemical, foam or water spray. Extinguishing media which must not be used for safety reasons: Water jet
Special protective equipment for fire­fighting: Wear self contained breathing apparatus, protective
clothing and goggles. Section 6. Accidental Release Measures
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable
container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Personal precautions: Wear suitable protective clothing and eye protection to prevent shin and eye contact. Environmental­protection measures: Keep the area isolated and do not allow contamination to enter the
sewerage system. Do not flush with water. Procedures for cleaning/absorption: Contain/absorb the spillage with a suitable inert absorbent material. Collect contaminated material and place in covered, labelled containers for disposal. Section 7. Handling and Storage
Handling: Do not swallow and avoid contact with eyes, skin and clothing. Use only in a well­ventilated
area. Wear appropriate personal protective clothing and equipment. Storage: Keep out of reach of children and animals. Keep in the original container in a cool, dry, well­ ventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect
against contamination. Section 8. Exposure Controls/Personal Protection
Occupational exposure limits: None assigned. Engineering measures to reduce exposure: Ensure adequate ventilation, especially in confined areas. Personal protective equipment:
Respiratory protection: Wear a respirator with a charcoal filter following the manufacturer’s instructions
for use. Eye protection: Wear safety goggles conforming to BS 2092. Hand protection: Wear PVC or nitrile gloves. Skin and body protection: Lightweight protective clothing should be used to prevent contamination when
dealing with the concentrate or spray. Industrial Hygiene: Immediately change contaminated clothing, dispose of if decontamination is not
feasible. Section 9. Physical and Chemical Properties
Physical State: White waxy crystal
Vapor Pressure: Not available. Evaporation Rate: Not available. Viscosity: Not available. Boiling Point: 265℃
Melting Point: 74­75 ℃
Specific Gravity/Density:1.409g/cm3 Solubility： In water c. 1 kg/l (23 篊). Readily soluble in methanol, ethanol, isopropanol, acetone, diethyl
ether, and other polar organic solvents. Sparingly soluble in non­polar organic solvents such as benzene and
toluene. Insoluble in kerosene and diesel oil. Section 10. Stability and Reactivity
Chemical Stability: Stable at room temperature in closed containers under normal storage and handling
conditions. Conditions to Avoid: Incompatible materials, excess heat, strong oxidants, exposure to moist air or water. Incompatibilities with Other Materials: Oxidizing agents, moisture. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, oxides of phosphorus, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11. Toxicological Information
Oral： Acute oral LD50 for rats 3030 mg/kg
Skin and eye： Acute percutaneous LD50 for rabbits 1560 mg/kg
Irritation: Irritating to skin and eyes. Inhalation： LC50 (4 h) for rats 4.52 mg/l
Section 12. Ecological Information
Birds: Acute oral LD50 for bobwhite quail 1072 mg/kg (tech.). Dietary LC50 (8 d) for bobwhite quail
>5000 ppm in diet (tech.). Fish: LC50 (96 h) for carp >140, rainbow trout 720 mg/l (tech.). Daphnia EC50 (48 h) 1000 mg/l (tech.). Algae: EC50 (24­48 h) for Chlorella vulgaris 32 mg/l. Other aquatic spp. Low toxicity. Bees: Harmless to bees. Worms: Not toxic to earthworms. Section 13. Disposal Considerations
Do not contaminate water, food, or feed by storage or disposal. Excess pesticide resulting from the use of
this product may be disposed of on site according to label directions or at an approved waste disposal
facility. Follow all local, state, and federal requirements for disposal. Section 14. Transport Information
Hazard Class: 8
UN Number: 3261
Packing Group: II
Section 15. Regulatory Information
Cercla: None
SARA TITILE III, Section 313 Toxic Chemicals: None
PROPOSITION 65(CA): None
Section 16. Other Information
*************************************************************************************** The information above is believed to be accurate and represents the best information currently available to
us. However, we make no warranty of merchant ability or any other warranty, express or implied, with
respect to such information, and Honbor Industrial Co., Ltd. assumes no legal responsibility for use or
reliance upon these data. The date on this sheet relates only to the specific material designated herein, and
users should make their own investigations to determine the suitability of the information for their particular
purposes. In no way shall Honbor Industrial Co., Ltd. be liable for ant claims, losses, or damages of any third
party or for lost profits or any special, indirect, incidental, consequential or exemplary damages. SINO OCEAN ENTERPRISES LIMITED.

Kết quả (Việt) 1:

AN TOÀN DATA SHEETEthephon 85% TCPhần 1. Nhận dạng sản phẩm và công tyTên sản phẩm: Ethephon 85% TCCông thức phân tử: C2H6ClO3PTrọng lượng phân tử: 144.5Tên hóa học: 2chloroethylphosphonic axitCAS số: 16672870Nhà cung cấp: Trung đại dương các doanh nghiệp LIMITED. Địa chỉ: RM D, 12/F., SAI WAN HO BLDG., 4556 SAI WAN HO STREET, Hồng KôngPhần 2. Thành phần/thông tin về thành phầnThành phần CAS số Nội dung (%)Ethephon 16672870 85.0Các thành phần khác 15.0Phần 3. Xác định mối nguy hiểmMắt: nguyên nhân gây kích ứng mắt. Da: Nguyên nhân gây kích ứng da. Uống: Có thể gây ra kích thích đường tiêu hóa với buồn nôn, nôn mửa và tiêu chảy. Có thể làm timrối loạn. Có thể gây ra trầm cảm hệ thần kinh trung ương. Hít phải: Gây ra kích thích đường hô hấp. Có thể có hại nếu hít vào. Có thể gây ra bất thường tim. Mãn tính: Hiệu ứng có thể bị chậm trễ. Phần 4. Các biện pháp hỗ trợ đầu tiênUống: Nếu nuốt, rửa ra khỏi miệng với nước cung cấp người là ý thức. Gọi một bác sĩ. Hít phải: Nếu hít vào, loại bỏ để không khí trong lành. Nếu không thở cho hô hấp nhân tạo. Nếu hơi thở là khó khăn, cung cấp cho oxy. Da: Trong trường hợp da tiếp xúc, tuôn ra với số tiền phong phú của nước cho ít nhất 15 phút. Loại bỏbị ô nhiễm quần áo và giày dép. Gọi một bác sĩ. Mắt: trong trường hợp tiếp xúc với mắt, tuôn ra với số tiền phong phú của nước cho ít nhất 15 phút. Đảm bảoxả nước đầy đủ bằng cách tách mí mắt với ngón tay. Gọi một bác sĩ. Phần 5. Biện pháp chữa cháyThông tin chung: Như trong bất kỳ cháy, mặc một selfcontained máy pressuredemand, MSHA/NIOSH (đã được phê duyệt hoặc tương đương), và bảo vệ đầy đủ thở. Trong một ngọn lửa, khó chịu và có độc tính caokhí có thể được tạo ra bởi nhiệt phân hủy hoặc đốt. Hơi có thể nặng hơn không khí. Họ có thểLan rộng dọc theo mặt đất và thu thập ở khu vực thấp hoặc hạn chế. Tiếp xúc với kim loại có thể phát triển dễ cháykhí hydro. Thùng chứa có thể phát nổ khi bị nung nóng. Noncombustible, chất chính nó không cháy nhưngcó thể phân hủy sau khi hệ thống sưởi để sản xuất hơi khó chịu, ăn mòn và/hoặc độc hại. Các dòng chảy từ kiểm soát hỏa lực hoặcpha loãng nước có thể gây ô nhiễm. Chữa phương tiện truyền thông: Không nhận được nước bên trong container. Đối với đám cháy nhỏ, sử dụng khô hóa học, carbonđiôxít, hoặc tia nước phun. Đối với đám cháy lớn, sử dụng khô hóa chất, khí carbon dioxide, alcoholresistant bọt hoặc nướcphun. Mát mẻ container với lũ lụt một lượng nước cho đến khi tốt sau khi lửa ra ngoài. Phù hợp chữa phương tiện truyền thông: Giặt trơ phun hóa chất, bọt hoặc nước. Chữa phương tiện truyền thông mà không phải được sử dụng cho lý do an toàn: nước máy bay phản lựcĐặc biệt thiết bị bảo vệ cho chữa cháy: mặc tự chứa bộ máy thở, bảo vệQuần áo và kính. Phần 6. Các biện pháp tình cờ phát hànhTràn/rò rỉ: Hấp thụ tràn với vật chất trơ (ví dụ như vermiculite, cát hoặc trái đất), sau đó diễn ra ở thích hợpcontainer. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Personal precautions: Wear suitable protective clothing and eye protection to prevent shin and eye contact. Environmental­protection measures: Keep the area isolated and do not allow contamination to enter thesewerage system. Do not flush with water. Procedures for cleaning/absorption: Contain/absorb the spillage with a suitable inert absorbent material. Collect contaminated material and place in covered, labelled containers for disposal. Section 7. Handling and StorageHandling: Do not swallow and avoid contact with eyes, skin and clothing. Use only in a well­ventilatedarea. Wear appropriate personal protective clothing and equipment. Storage: Keep out of reach of children and animals. Keep in the original container in a cool, dry, well­ ventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protectagainst contamination. Section 8. Exposure Controls/Personal ProtectionOccupational exposure limits: None assigned. Engineering measures to reduce exposure: Ensure adequate ventilation, especially in confined areas. Personal protective equipment:Respiratory protection: Wear a respirator with a charcoal filter following the manufacturer’s instructionsfor use. Eye protection: Wear safety goggles conforming to BS 2092. Hand protection: Wear PVC or nitrile gloves. Skin and body protection: Lightweight protective clothing should be used to prevent contamination whendealing with the concentrate or spray. Industrial Hygiene: Immediately change contaminated clothing, dispose of if decontamination is notfeasible. Section 9. Physical and Chemical PropertiesPhysical State: White waxy crystalVapor Pressure: Not available. Evaporation Rate: Not available. Viscosity: Not available. Boiling Point: 265℃Melting Point: 74­75 ℃Specific Gravity/Density:1.409g/cm3 Solubility： In water c. 1 kg/l (23 篊). Readily soluble in methanol, ethanol, isopropanol, acetone, diethylether, and other polar organic solvents. Sparingly soluble in non­polar organic solvents such as benzene andtoluene. Insoluble in kerosene and diesel oil. Section 10. Stability and ReactivityChemical Stability: Stable at room temperature in closed containers under normal storage and handlingconditions. Conditions to Avoid: Incompatible materials, excess heat, strong oxidants, exposure to moist air or water. Incompatibilities with Other Materials: Oxidizing agents, moisture. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, oxides of phosphorus, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11. Toxicological InformationOral： Acute oral LD50 for rats 3030 mg/kgSkin and eye： Acute percutaneous LD50 for rabbits 1560 mg/kgIrritation: Irritating to skin and eyes. Inhalation： LC50 (4 h) for rats 4.52 mg/lSection 12. Ecological InformationBirds: Acute oral LD50 for bobwhite quail 1072 mg/kg (tech.). Dietary LC50 (8 d) for bobwhite quail>5000 ppm in diet (tech.). Fish: LC50 (96 h) for carp >140, rainbow trout 720 mg/l (tech.). Daphnia EC50 (48 h) 1000 mg/l (tech.). Algae: EC50 (24­48 h) for Chlorella vulgaris 32 mg/l. Other aquatic spp. Low toxicity. Bees: Harmless to bees. Worms: Not toxic to earthworms. Section 13. Disposal ConsiderationsDo not contaminate water, food, or feed by storage or disposal. Excess pesticide resulting from the use ofthis product may be disposed of on site according to label directions or at an approved waste disposalfacility. Follow all local, state, and federal requirements for disposal. Section 14. Transport InformationHazard Class: 8UN Number: 3261Packing Group: IISection 15. Regulatory InformationCercla: NoneSARA TITILE III, Section 313 Toxic Chemicals: NonePROPOSITION 65(CA): NoneSection 16. Other Information*************************************************************************************** The information above is believed to be accurate and represents the best information currently available tous. However, we make no warranty of merchant ability or any other warranty, express or implied, withrespect to such information, and Honbor Industrial Co., Ltd. assumes no legal responsibility for use or
reliance upon these data. The date on this sheet relates only to the specific material designated herein, and
users should make their own investigations to determine the suitability of the information for their particular
purposes. In no way shall Honbor Industrial Co., Ltd. be liable for ant claims, losses, or damages of any third
party or for lost profits or any special, indirect, incidental, consequential or exemplary damages. SINO OCEAN ENTERPRISES LIMITED.