Antoine Laurent de Lavoisier (cũng Antoine Lavoisier sau cuộc cách mạng Pháp; 26 tháng 8 năm 1743-8 tháng 5 năm 1794; [ 1] cách phát âm tiếng Pháp: [ɑ̃twan lɔʁɑ̃ də lavwazje]) là một nhà quý tộc Pháp và nhà hóa học người Trung tâm của cuộc cách mạng hóa học thế kỷ 18 và một ảnh hưởng lớn trên cả hai lịch sử hóa học và lịch sử của sinh học. [2] ông được coi là rộng rãi trong văn chương là "cha đẻ của hóa học hiện đại". [3] nhãn này, Tuy nhiên, là nhiều hơn một sản phẩm của Lavoisier của kỹ năng nổi tiếng như là một promoter tự và underplays của mình phụ thuộc vào thiết bị, thí nghiệm và ý tưởng của nhà hóa học khác. [4]Nó nói chung chấp nhận rằng những thành tựu tuyệt vời của Lavoisier hóa học chủ yếu xuất phát từ của mình thay đổi khoa học từ một chất lượng sang một định lượng. Lavoisier nổi tiếng cho công trình phát hiện vai trò phát ôxy trong đốt cháy. Ông được công nhận và đặt tên là oxy (1778) và hydro (1783) và chống lại thuyết phlogiston. Lavoisier đã giúp xây dựng hệ thống số liệu, đã viết danh sách mở rộng đầu tiên của yếu tố, và đã giúp để cải cách hóa danh pháp. Ông dự đoán sự tồn tại của silic (1787) [5] và cũng là người đầu tiên để thành lập lưu huỳnh là một phần tử (1777) chứ không phải là một hợp chất. [6] ông phát hiện ra rằng, mặc dù vấn đề có thể thay đổi hình thức hoặc hình dạng của nó, khối lượng của nó luôn luôn vẫn giữ nguyên.Lavoisier là một thành viên mạnh mẽ của một số hội đồng quý tộc, và người quản trị của Ferme Générale. Ferme générale là một trong các thành phần đặt ghét của Bungary bần vì lợi nhuận mất chi phí của nhà nước, các bí mật của các điều khoản của hợp đồng của mình, và bạo lực của các đại lý vũ trang. [7] tất cả các hoạt động chính trị và kinh tế cho phép anh ta để tài trợ nghiên cứu khoa học của ông. Ở đỉnh cao của cuộc cách mạng Pháp, ông bị cáo buộc của Jean-Paul Marat bán pha trộn thuốc lá và của tội phạm khác, và cuối cùng guillotined một năm sau cái chết của Marat.Nội dungTiểu sửThời niên thiếu và giáo dụcCông trình khoa học đầuFerme générale và hôn nhânOxy lý thuyết của sự cháyJoseph Black "cố định máy"Joseph PriestleyEaster cuốn hồi kýTháo dỡ thuyết phlogistonỦy ban thuốc súngTiên phong của stoichiometryDanh pháp hóa họcTiểu luận của hóa họcSinh lý công việcNgày cuối cùng và thực hiệnPost-mortemDi sảnTác phẩm đã chọnTrong bản dịchGhi chúĐọc thêmLiên kết ngoàiVề công việc của mìnhTác phẩm của mìnhChỉnh sửa tiểu sửThời niên thiếu và giáo dục chỉnh sửaAntoine-Laurent Lavoisier was born to a wealthy family in Paris on 26 August 1743. The son of an attorney at the Parliament of Paris, he inherited a large fortune at the age of five with the passing of his mother.[8] Lavoisier began his schooling at the Collège des Quatre-Nations, University of Paris, (known as the Collège Mazarin) in Paris in 1754 at the age of 11. In his last two years (1760–1761) at the school, his scientific interests were aroused, and he studied chemistry, botany, astronomy, and mathematics. In the philosophy class he came under the tutelage of Abbé Nicolas Louis de Lacaille, a distinguished mathematician and observational astronomer who imbued the young Lavoisier with an interest in meteorological observation, an enthusiasm which never left him. Lavoisier entered the school of law, where he received a bachelor's degree in 1763 and a licentiate in 1764. Lavoisier received a law degree and was admitted to the bar, but never practiced as a lawyer. However, he continued his scientific education in his spare time.Early scientific work EditLavoisier's education was filled with the ideals of the French Enlightenment of the time, and he was fascinated by Pierre Macquer's dictionary of chemistry. He attended lectures in the natural sciences. Lavoisier's devotion and passion for chemistry were largely influenced by Étienne Condillac, a prominent French scholar of the 18th century. His first chemical publication appeared in 1764. From 1763 to 1767, he studied geology under Jean-Étienne Guettard. In collaboration with Guettard, Lavoisier worked on a geological survey of Alsace-Lorraine in June 1767. In 1764 he read his first paper to the French Academy of Sciences, France's most elite scientific society, on the chemical and physical properties of gypsum (hydrated calcium sulfate), and in 1766 he was awarded a gold medal by the King for an essay on the problems of urban street lighting. In 1768 Lavoisier received a provisional appointment to the Academy of Sciences. In 1769, he worked on the first geological map of France.Ferme générale and marriage EditPortrait of Antoine-Laurent Lavoisier and his wife by Jacques-Louis David, ca. 1788At the age of 26, around the time he was elected to the Academy of Sciences, Lavoisier bought a share in the Ferme générale, a tax farming financial company which advanced the estimated tax revenue to the royal government in return for the right to collect the taxes. Lavoisier attempted to introduce reforms in the French monetary and taxation system to help the peasants. While in government work, he helped develop the metric system to secure uniformity of weights and measures throughout France. Lavoisier consolidated his social and economic position when, in 1771 at age 28, he married Marie-Anne Pierrette Paulze, the 13-year-old daughter of a senior member of the Ferme générale.[9] She was to play an important part in Lavoisier's scientific career—notably, she translated English documents for him, including Richard Kirwan's Essay on Phlogiston and Joseph Priestley's research. In addition, she assisted him in the laboratory and created many sketches and carved engravings of the laboratory instruments used by Lavoisier and his colleagues for their scientific works.Madame Lavoisier edited and published Antoine's memoirs (whether any English translations of those memoirs have survived is unknown as of today) and hosted parties at which eminent scientists discussed ideas and problems related to chemistry.[10] For 3 years following his entry into the Ferme générale, Lavoisier's scientific activity diminished somewhat, for much of his time was taken up with official Ferme générale business. He did, however, present one important memoir to the Academy of Sciences during this period, on the supposed conversion of water into earth by evaporation. By a very precise quantitative experiment Lavoisier showed that the "earthy" sediment produced after long-continued reflux heating of water in a glass vessel was not due to a conversion of the water into earth but rather to the gradual disintegration of the inside of the glass vessel produced by the boiling water.Oxygen theory of combustion EditAntoine Lavoisier's famous phlogiston experiment. Engraving by Mme Lavoisier in the 1780s taken from Traité élémentaire de chimie (Elementary treatise on chemistry)During late 1772 Lavoisier turned his attention to the phenomenon of combustion, the topic on which he was to make his most significant contribution to science. He reported the results of his first experiments on combustion in a note to the Academy on 20 October, in which he reported that when phosphorus burned, it combined with a large quantity of air to produce acid spirit of phosphorus, and that the phosphorus increased in weight on burning. In a second sealed note deposited with the Academy a few weeks later (1 November) Lavoisier extended his observations and conclusions to the burning of sulfur and went on to add that "what is observed in the combustion of sulfur and phosphorus may well take place in the case of all substances that gain in weight by combustion and calcination: and I am persuaded that the increase in weight of metallic calces is due to the same cause."
Joseph Black's "fixed air" Edit
During 1773 Lavoisier determined to review thoroughly the literature on air, particularly "fixed air," and to repeat many of the experiments of other workers in the field. He published an account of this review in 1774 in a book entitled Opuscules physiques et chimiques (Physical and Chemical Essays). In the course of this review he made his first full study of the work of Joseph Black, the Scottish chemist who had carried out a series of classic quantitative experiments on the mild and caustic alkalies. Black had shown that the difference between a mild alkali, for example, chalk (CaCO3), and the caustic form, for example, quicklime (CaO), lay in the fact that the former contained "fixed air," not common air fixed in the chalk, but a distinct chemical species, now understood to be carbon dioxide (CO2), which was a constituent of the atmosphere. Lavoisier recognized that Black's fixed air was identical with the air evolved when metal calces were reduced with the charcoal and even suggested that the air which combined with metals on calcination and increased the weight might be Black's fixed air, that is, CO2.
Joseph Priestley Edit
Joseph Priestley, an English chemist known for isolating oxygen, which he termed "dephlogisticated air."
In the spring of 1774 Lavoisier carried out experiments on the calcination of tin and lead in sealed vessels which conclusively confirmed that the increase in weight of metals in combustion was due to combination with air. But the question remained about whether it was combination with common atmospheric air or with only a part of atmospheric air. In October the English chemist Joseph Priestley visited Paris, where he met Lavoisier and told him of the air which he had produced by heating the red calx of mercury with a burning glass and which had supported combustion with extreme vigor. Priestley at this time was unsure of the nature of this gas, but he felt that it was an especially pure form of common air. Lavoisier carried out his own researches on this peculiar substance. The result was his famous memoir On the Nature of the Principle Which Combines with Metals during Their Calcination and Increases Their Weight, read to the Academy on 26 April 1775 (commonly referred to
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