(ii) The research on well-established rules and correlations between molecular structures of the adopted ILs and the morphologies of the resulting inorganic materials is limited. 53. We believe that the realization of the general trends may be utilized in the rational design of desired inorganic materials with the desired polymorph and the desired morphology using ILs. For thisregard, this review will focus on the rational design of ionic liquids and an understanding of the ionic liquid'seffectat the molecular level based on solution-phase methods. Althoughthe use of ILs for the synthesis of inorganic nanomaterials has been reviewed in some inspiring short accounts or perspectives,3,5,6,12,54,55 a relatively comprehensive and fundamentalreview of this subject is still lacking, especially considering the rational design of ionic liquids at the molecular level.
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